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NO分解催化剂的研究进展
引用本文:李海龙,肖萍,王涛,朱君江,李金林.NO分解催化剂的研究进展[J].中国科学:化学,2014(12):1951-1965.
作者姓名:李海龙  肖萍  王涛  朱君江  李金林
作者单位:中南民族大学催化材料科学湖北省暨国家民委-教育部共建重点实验室;
基金项目:国家自然科学基金(21203254);教育部留学回国人员科研启动基金(BZY11055)资助
摘    要:本文对用于NO直接催化分解的贵金属、金属氧化物、钙钛矿型复合金属氧化物、分子筛和碳氮化合物5种代表性催化材料上NO的催化分解性能及反应机理进行了综述.介绍了各种催化材料在用于NO分解反应中所取得的成就和存在的问题.此外,也对计算机模拟技术在NO催化分解中的应用进行了简单介绍,说明计算机技术是一种重要的实验研究辅助手段,有助于对实验现象的理解并为开发新型催化材料提供理论指导.

关 键 词:NO直接分解  催化剂  反应机理  理论模拟

Recent progress on catalysts used for NO decomposition
LI HaiLong,XIAO Ping,WANG Tao,ZHU JunJiang,LI JinLin.Recent progress on catalysts used for NO decomposition[J].Scientia Sinica Chimica,2014(12):1951-1965.
Authors:LI HaiLong  XIAO Ping  WANG Tao  ZHU JunJiang  LI JinLin
Institution:(Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, Hubei Province, South-Central University for Nationalities, Wuhan 430074, China)
Abstract:This work overviewed the catalytic performance and reaction mechanism of NO direct decomposition conducted on five representative catalysts, including noble metals, metal oxides, perovskite-type oxides, Cu-ZSM-5 and graphitic carbon nitride(g-C3N4). The achievements and problems of using such materials for NO decomposition were described and discussed. In addition, applications of computer technology in simulating the catalytic NO decomposition process over different catalytic materials were also introduced. The computer technology is an effective means in assisting the explanation of phenomena observed in experiments and could give constructive directions in exploring new catalytic material for NO decomposition.
Keywords:NO decomposition  catalysts  mechanism  theoretical calculation
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