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A reliable solid phase microextraction-gas chromatography–triple quadrupole mass spectrometry method for the assay of selenomethionine and selenomethylselenocysteine in aqueous extracts: Difference between selenized and not-enriched selenium potatoes
Authors:Emanuela Gionfriddo  Attilio NaccaratoGiovanni Sindona  Antonio Tagarelli
Institution:Dipartimento di Chimica, Università della Calabria, Via Pietro Bucci Cubo 12/C, I-87030 Arcavacata di Rende, CS, Italy
Abstract:A new analytical approach is exploited in the assay of selenium speciation in selenized and not selenium enriched potatoes based on the widely available solid-phase microextraction (SPME) coupled to-GC–triple quadrupole mass spectrometry (SPME-GC–QqQ MS) method.
Keywords:Selenoamino acids  Selenized potatoes  SPME  Tandem mass spectrometry  Selenium speciation  Alkyl chloroformates
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