Water soluble cucurbit[6]uril derivative as a potential Xe carrier for 129Xe NMR-based biosensors |
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Authors: | Kim Byoung Soo Ko Young Ho Kim Youngkook Lee Hyeong Ju Selvapalam N Lee Hee Cheon Kim Kimoon |
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Institution: | Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea. |
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Abstract: | The water soluble cucurbit6]uril derivative CB*6] forms a thermodynamically and kinetically stable host-guest complex with xenon in water, the binding affinity of which is about 3 x 10(3) M(-1), comparable to those of cryptophanes, suggesting that it may serve as an effective molecular "carrier" for 129Xe NMR-based biosensors. |
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