| Practical reduction of imines by NaBH4/alumina under solvent-free conditions： An efficient route to secondary amine |
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| 作者姓名： | Foad Kazemi Ali Reza Kiasat Ebrahim Sarvestani |
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| 作者单位： | a Institute for Advanced Studies in Basic Sciences(IASBS), Zanjan 45195, Iran;b Chemistry Department, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, Iran |
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| 基金项目： | Partial support for this work by Chamran University Research Council are gratefully acknowledged. |
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| 摘 要： | Sodium borohydride supported on alumina reduces imines to the corresponding secondary amines in high to excellent isolated yields under solvent-free conditions. Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogen, nitro, and cyano groups.
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| 关 键 词： | 亚胺 次级胺 溶剂 氢硼化钠 |
| 收稿时间： | 27 March 2008 |
Practical reduction of imines by NaB H4/alumina under solvent-free conditions:An efficient route to secondary amine |
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| Foad Kazemi,Ali Reza Kiasat,Ebrahim Sarvestani.Practical reduction of imines by NaB H4/alumina under solvent-free conditions:An efficient route to secondary amine[J].Chinese Chemical Letters,2008,19(10):1167-1170. |
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| Authors: | Foad Kazemi Ali Reza Kiasat Ebrahim Sarvestani |
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| Institution: | a Institute for Advanced Studies in Basic Sciences(IASBS), Zanjan 45195, Iran;b Chemistry Department, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, Iran |
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| Abstract: | Sodium borohydride supported on alumina reduces imines to the corresponding secondary amines in high to excellent isolated yields under solvent-free conditions.Noteworthy is that highly chemoselective reactions were achieved in the presence of other functional groups such as halogen,nitro,and cyano groups. |
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| Keywords: | Imine Secondary amine Solvent free Reduction Sodium borohydride |
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