| 热分析与气相色谱联用研究一水合草酸氢钾 |
| |
| 引用本文： | 杜廷发,张世进.热分析与气相色谱联用研究一水合草酸氢钾[J].无机化学学报,1999,15(4):531-535. |
| |
| 作者姓名： | 杜廷发 张世进 |
| |
| 作者单位： | 1. 国防科技大学,材料工程与应用化学系,长沙,410073
2. 中国人民解放军89810部队,马兰,841700 |
| |
| 摘 要： | 用热分析与气相色谱联用技术(TA-GC)研究KHC2O4·H2O的热分解表明，在空气和氦气当中，开始时缓慢分解，放出结晶水。接着KHC2O4快速分解成K2C2O4，并释放出一些气体产物：O2(分解初期)、CO、CO2和H2O。讨论了KHC2O4的分解机理。
|
| 关 键 词： | 热分解 一水合草酸氢钾 逸出气体分析(EGA) TA-GC联用 |
STUDIES ON THE THERMAL DECOMPOSITION OF POTASSIUM HYDROGEN OXALATE MONOHYDRATE BY COMBINED THERMAL ANALYSIS AND GAS CHROMATOGRAPHY |
| |
| DU Ting-Fa and ZHANG Shi-Jin.STUDIES ON THE THERMAL DECOMPOSITION OF POTASSIUM HYDROGEN OXALATE MONOHYDRATE BY COMBINED THERMAL ANALYSIS AND GAS CHROMATOGRAPHY[J].Chinese Journal of Inorganic Chemistry,1999,15(4):531-535. |
| |
| Authors: | DU Ting-Fa and ZHANG Shi-Jin |
| |
| Institution: | Department of Material Engineering and Applied Chemistry, National University of Defence Technology, Changsha 410073 and PLA 89810 Troops, Xinjiang Malan 841700 |
| |
| Abstract: | The thermal decomposition of KHC2O4·H2O was investigated by means of discontinuous simultaneous techniques of thermal analysis and gas chromatography (TA-GC). In air and helium the decomposition of KHC2O4·H2O was initially a slow dehydration process of the monohydrate, followed by a rapid decomposition of KHC2O4 to K2C2O4 with the production of some gaseous products, O2 (initial stage of decomposition), CO, CO2 and H2O. The decomposition mechanism of KHC2O4 was discussed. |
| |
| Keywords: | thermal decomposition potassium hydrogen oxalate monohydrate combined TA-GC evolved gas analysis (EGA) |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
