Michael reactions withtrans-3-isopropenyl-2-phenylthiocyclopentan-1-one andtrans-3-isopropenyl-2-phenylsulfonylcyclopentan-1-one |
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| Authors: | V. V. Veselovsky B. T. Zhuzbaev K. M. Turdybekov S. M. Adekenov Yu. T. Struchkov A. M. Moiseenkov |
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| Affiliation: | (1) N.D.Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow, Russian Federation;(2) A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, Russian Federation |
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| Abstract: | The condensation of methyl acrylate with the title  -ketosulfide and -ketosulfone was studied. The primary adduct of -ketosulfone with acrolein readily undergoes intramolecular aldolization to give bicyclo[3.2.1]octane derivatives. The molecular structure of one of them was elucidated by X-ray analysis.Deceased Nov., 1, 1992.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 118–122, January, 1993. |
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| Keywords: | cyclopentanone ![]("</a) /content/r4264214w752522v/xxlarge946.gif" alt=" beta" align=" MIDDLE" BORDER=" 0" >-ketosulfide /content/r4264214w752522v/xxlarge946.gif" alt=" beta" align=" MIDDLE" BORDER=" 0" >-ketosulfone Michael reaction methyl acrylate acrolein bicyclo[3.2.1]octane derivatives X-ray analysis |
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