Spectroscopic and electrochemical studies of ruthenium and osmium complexes of salicylideneimine-2-thiophenol Schiff base

The reactions between M(3)(CO)(12)], M = Ru and Os, and salicylideneimine-2-thiophenol Schiff base in THF under reflux gave Ru(CO)(4)(satpH)] and Os(CO)(3)(satpH(2))] complexes. Structures of the two complexes were proposed on the basis of spectroscopic studies. Magnetic study of Ru(CO)(4)(satpH)] suggested that a change in oxidation state of the ruthenium atom from zero to +1 was achieved via oxidative addition of the SH group with a proton displacement to give a low-spin d(7) electronic configuration. UV-Vis spectra of the two complexes in different solvents exhibited visible bands due to metal-to-ligand charge transfer. Electrochemical investigation of the free ligand and complexes showed some cathodic and anodic irreversible peaks due to interconversions through electron transfer.