flow injection systems wiht inductively-coupled argon plasma atomic emission spectrometry: Part 2. The generalized standard addition method |
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Authors: | EAG Zagatto AO Jacintho FJ Krug BF Reis |
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Institution: | Centro de Energia Nuclear na Agricultura USP, 13400 Piracicaba, S.P. Brazil |
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Abstract: | In multicomponent analysis by inductively-coupled argon plasma emission spectrometry, the generalized standard addition method is useful in overcoming matrix and/or spectral interferences. As this method requires many standard additions, it becomes cumbersome when done manually if many elements are to be determined. By using a flow injection system, the standard addtion manipulations required can be significantly simplified and completed within a shorter period of time with much less sample material. A flow injection system with merging zones is used to demonstrate the method for analyses of a Ni/Cu/Zn standard and of alloys. The reproducibility of measurements of the injected sample, with or without additions of standards is always better than 99%. The results obtained compare well with those obtained by the manual procedure and also with those obtained by atomic absorption spectrometry. |
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