The application of strongly reducing agents in flow injection analysis: Part 1. Chromium(II) and vanadium(II) |
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Authors: | R.C. Schotohrst J.M. Reijn H. Poppe G. Den Boef |
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Affiliation: | Laboratory for Analytical Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam The Netherlands |
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Abstract: | Many reagenst cannot easily be applied in quantitative analysis, because of their instability under atmospheric conditions. When such reagents are prepared in a flowing stream, their applicability is very promising; for example, in flow injection analysis, a reagent need be stable only for 20–30 s. The application of chromium(II) and vanadium(II) in flow injection analysis is described. Nitrate and nitrile can be determined in the concentration range 5 × 10?5?5 × 10?3. Calibration graphs show good linearity. |
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