A new convinient synthesis of 3(2H)-furanones |
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| Affiliation: | 1. Selvita Services Sp. Z o. o., Bobrzynskiego 14, 30-348 Krakow, Poland;2. Sandoz GmbH, Biochemiestr. 10, A-6550 Kundl, Austria;1. Department of Chemical and Biomolecular Engineering, School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Payupnai, Wang Chan, Rayong 21210, Thailand;2. Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Payupnai, Wang Chan, Rayong 21210, Thailand;3. Normandie University, SMS, EA 3233 University of Rouen, Crystal Genesis Unit, 76821 Mont Saint-Aignan Cedex, France;1. Center for Nanomedicine and Theranostics, Department of Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800, Kgs. Lyngby, Denmark;2. Max-Eder Group Experimental Therapies for Hematologic Malignancies, German Cancer Research Center (DKFZ), Germany;3. Clinical Cooperation Unit Molecular Hematology/Oncology, German Cancer Research Center (DKFZ) and Dept. of Internal Medicine V, University of Heidelberg, Heidelberg, Germany;1. Université de Lorraine, Laboratoire Réactions et Génie des Procédés, UMR 7274, Nancy, F-54001, France;2. CNRS, Laboratoire Réactions et Génie des Procédés, UMR 7274, Nancy, F-54001, France;1. Departamento de Química, Universidade Federal de Santa Catarina, Florianópolis, SC 88040-900, Brazil;2. Departamento de Ciências Farmacêuticas, Universidade Federal de Santa Catarina, Florianópolis, SC 88040-900, Brazil;3. Departamento de Bioquímica, Universidade Federal de Santa Catarina, Florianópolis, SC 88040-900, Brazil;4. Departamento de Análises Clínicas, Universidade Federal de Santa Catarina, Florianópolis, SC 88040-900, Brazil |
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| Abstract: | A selective oxidative fission of the heterocyclic nucleus of 5-methyl-2-(acylmethyl)furans or 2-(5-methyl-2-furyl)-1,3-dicarbonyl compounds by m-chloroperbenzoic acid allows the easy synthesis of the 3(2H)-furanone system. |
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