Regiospecific and highly stereoselective allylation of aldehydes with allyltrifluorosilane activated by fluoride ions. |
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| Affiliation: | 1. Centre for Natural Products & Traditional Knowledge, CSIR – Indian Institute of Chemical Technology, Hyderabad 500007, India;2. Academi of Scientific and Innovative Research-Postal staff college Area, Sector 19, Kamla Nehru Nagar, Ghaziabad, Utter Pradesh 201002, India;3. Department of Applied Biology, CSIR – Indian Institute of Chemical Technology, Hyderabad 500007, India;4. Qstatix Private Limited, Hyderabad 500035, India;1. Cumhuriyet University, Faculty of Education, Department of Science Education, 58040, Sivas, Turkey;2. Cumhuriyet University, Faculty of Education, Department of Basic Education, 58040, Sivas, Turkey;1. Institute of Catalysis for Energy and Environment, College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China;2. State Key Laboratory for Mechanical Behavior of Materials, Xi’an Jiaotong University, Xi’an 710049, China;3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova, dom 28, Moscow, 119991, Russia;2. Peoples'' Friendship University of Russia (RUDN University), ul. Miklukho-Maklaya, dom 6, Moscow, 117198, Russia;3. Pirogov Russian National Research Medical University, ul. Ostrovitianova, dom 1, Moscow, 117997, Russia;4. National Research Center “Kurchatov Institute”, pl. Akad. Kurchatova, dom 1, Moscow, 123182, Russia;5. Boreskov Institute of Catalysis SB RAS, prosp. Akad. Lavrentieva, dom 5, Novosibirsk, 630090, Russia;6. Institut des Biomolécules Max Mousseron, UMR 5247, CNRS, Université de Montpellier, ENSCM, Site Triolet, Place Eugène Bataillon, 34095, Montpellier Cedex 5, France;7. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina, dom 4, Moscow, 119991, Russia;8. Plekhanov Russian University of Economics, Stremyannyi pereulok, dom 36, Moscow, 117997, Russia;1. Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland;2. Center for Advanced Technology, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland;1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Ulitsa Vavilova, Dom 28, 119991 Moscow, Russia;2. People''s Friendship University of Russia, Ulitsa Miklukho-Maklaya, Dom 6, 117198 Moscow, Russia;3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Ulitsa Kosygina, Dom 4, 119991 Moscow, Russia;4. Chair of Chemistry and Physics, Plekhanov Russian University of Economics, Stremyannyi Pereulok, Dom 36, 117997 Moscow, Russia |
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| Abstract: | Allyltrifluorosilane/CsF systems form pentacoordinate allylsiliconates which undergo chemoselective, regiospecific and highly stereoselective allylation of aldehydes, presumably via six-membered cyclic transition states. |
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