Concise asymmetric synthesis of (5S, 6S)- aeginetolide and (5S)- dihydroactinidiolide |
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| Affiliation: | 1. Graduate Institute of Natural Products, College of Pharmacy, Kaohsiung Medical University, Kaohsiung 80708, Taiwan;2. Center for Infectious Disease and Cancer Research, Kaohsiung Medical University, Kaohsiung 80708, Taiwan;3. Agricultural Biotechnology Research Center, Academia Sinica, Taipei 11529, Taiwan;4. Graduate Institute of Marine Biotechnology, National Dong Hwa University, Pingtung 94450, Taiwan;5. National Museum of Marine Biology & Aquarium, Pingtung 94450, Taiwan;6. Department of Marine Biotechnology and Resources, National Sun Yat-sen University, Kaohsiung 80424, Taiwan;7. School of Pharmacy, College of Pharmacy, China Medical University, Taichung 40402, Taiwan;8. Chinese Medicine Research and Development Center, China Medical University Hospital, Taichung 40402, Taiwan;9. Center for Molecular Medicine, China Medical University Hospital, Taichung 40402, Taiwan;10. Cancer Center, Kaohsiung Medical University Hospital, Kaohsiung 80708, Taiwan;1. Department of P.G studies and Research in Industrial Chemistry, Kuvempu University, Jnana Sahyadri, Shankaraghatta, Shimoga, Karnataka 577451, India;2. Department of Science and Humanities (Chemistry), Karpagam College of Engineering, Othakkal Mandapam, Coimbatore, Tamil Nadu 641032, India;3. Post Graduate and Research Department of Chemistry, Jamal Mohamed College, Bharathidasan University, Tiruchirapalli, India;4. Post Graduate and Research Department of Chemistry, Kasaragod Govt. College, Kannur University, Kannur, India;5. Anthem Biosciences Pvt. Ltd., No. 49, Bommasandra Industrial Area, Bangalore, Karnataka 560099, India |
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| Abstract: | An asymmetric deprotonation reaction allows for short syntheses of the lactones (5S, 6S)- Aeginetolide (1) and (5S)-Dihydroactinidiolide (2). |
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