Remarkable stabilizing effects of silyl group on furfuryl chlorides and furfuryl Grignard reagents |
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| Institution: | 1. Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, Shandong, China;2. School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, China;3. School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong, China;1. Departament de Química Orgànica, Facultat de Química, Universitat de València, Dr. Moliner 50, 46100 Burjassot, València, Spain;1. Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan;2. Office of Research, Innovation and Commercialization, Quaid-i-Azam University, Islamabad 45320, Pakistan;3. Department of Physics, University of Sargodha, Pakistan;4. H.E.J. Research Institute, University of Karachi, Karachi 75270, Pakistan;5. Department of Pharmacy, Faculty of Biological Sciences, Quaid-i-Azam University, Islamabad 45320, Pakistan |
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| Abstract: | By introducing a silyl group on their 5-position, furfuryl chlorides and the Grignard reagents have been stabilized remarkably and the Grignard reagents have exhibited unusual ambident behavior toward several electrophiles. |
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