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Stereospecific deoxygenation of 1,2-diols to olefins
Affiliation:1. College of Chemistry & Environment, South China Normal University, Guangzhou, 510006, China;2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032, China;1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China;2. Zhejiang Base of National Southern Pesticide Research Centre, Zhejiang Research Institute of Chemical Industry, Hangzhou 310023, China;1. Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia;2. Department of Pharmacy, University of Malaya, 50603 Kuala Lumpur, Malaysia;3. Nanotechnology & Catalysis Research Centre, NANOCEN, University of Malaya, 50603 Kuala Lumpur, Malaysia;4. Drug Design and Development Group, University of Malaya, 50603 Kuala Lumpur, Malaysia
Abstract:The 2-dimethylamino-1,3-dioxolane derivatives of 1,2-diols when treated with trifluoromethane sulfonic anhydride and diisopropylethylamine in toluene give the corresponding olefins stereospecifically under mild experimental conditions.
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