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Wittig-Horner reaction catalyzed by activated barium hydroxide in the presence of ultrasound
Institution:1. Institut des Biomolécules Max Mousseron, UMR 5247 CNRS, ENSCM, Université de Montpellier, France;2. School of Biological Sciences, The University of Hong Kong, Hong Kong Special Administrative Region;3. Leiden University Medical Center, Center for Proteomics and Metabolomics, Albinusdreef 2, 2300RC Leiden, The Netherlands
Abstract:The sonochemical Wittig-Horner reaction, catalyzed by an activated barium hydroxide catalyst in interfacial solid-liquid conditions leads to E-acrylates with very good yields. The sonochemical process takes place at room temperature and with lower catalyst weight and reaction time than the thermal process.
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