Regioselective 2-hydroxylation of 3-methoxyoestra-1,3,5(10)-trienes via chromium carbonyl complexes |
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| Affiliation: | 1. Key Lab of Education Ministry for Power Machinery and Engineering, School of Mechanical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, China;2. Gas Turbine Research Institute, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, 200240, China |
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| Abstract: | Deprotonation, with BuLi, of (n6arene) Cr(CO)3 complexes derived from 3-methoxyoestra-1,3,5(10) trienes followed by reaction with MoOPH leads to the 2-hydroxy-3-methoxy-derivatives in satisfactory yield. |
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