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Thiophenol promoted cyclization of enynes
Affiliation:1. School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Material, Jiangsu Normal University, Xuzhou, 221116, PR China;2. Department of Public Health, Xuzhou Medical College, Jiangsu, 221000, PR China;1. Department of Organic Chemistry, Institute of Chemistry, Saint Petersburg State University, Universitetskaya nab., 7/9, Saint Petersburg 199034, Russia;2. Department of Organic Chemistry, Saint Petersburg Institute of Technology (Technical University), Moskovskiy pr. 26, 190013 Saint Petersburg, Russia;3. Department of Chemistry, Saint Petersburg State Forest Technical University, Institutsky per., 5, Saint Petersburg 194021, Russia;1. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, United States;2. Department of Medicinal Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, United States
Abstract:Vinyl radicals generated by the addition of thiophenol to enynes have been shown to cyclize regioselectively giving cyclohexylidene thioethers.
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