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Isolierung und kristallstrukturanalyse eines titantetrachlorid-komplexes eines 1,3-diketons
Affiliation:1. Department of Physics, Karunya University, Coimbatore 641114, Tamilnadu, India;2. Department of Physics, KPR Institute of Engineering and Technology, Coimbatore 641407, Tamilnadu, India;3. Department of Physics, National University of Singapore, 1175423, Singapore;4. CSIR-Central Electrochemical Research Institute (CECRI)-Madras Unit, CSIR Madras Complex, Taramani, Chennai 600113, India
Abstract:Titanium tetrachloride forms a crystalline adduct with 3,3-dimethyl-2,4-pentanedione (2). This observation together with the structural data of complex 4 can help to understand the directive force of TiCl4 in stereoselective reductions of diketones.
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