Anti-markovnikov addition of nucleophiles to a non-conjugated olefin via single electron transfer photochemistry |
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| Affiliation: | 1. Chemistry Department, Faculty of Science, New Mansoura University, New Mansoura, Egypt;2. Plant Protection Research Institute, Agriculture Research Center, Giza 12618, Egypt;3. Chemistry Department, Faculty of Science, Mansoura University, Mansoura 35516, Egypt |
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| Abstract: | Nucleophilic solvent has been added regiospecifically in an anti-Markovnikov manner to a simple non-conjugated olefin, 1-methylcyclohexene, through single electron transfer induced photochemistry using the 1-cyanonaphthalene - biphenyl pair for achieving photooxidation. |
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