Synthesis and rearrangements of ortho-selenonium phenoxides |
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| Affiliation: | 1. Cleveland Clinic Lerner College of Medicine of Case Western Reserve University, Cleveland, OH, USA;2. Department of Quantitative Health Sciences, Cleveland Clinic, Cleveland, OH, USA;3. Department of Infectious Diseases, Cleveland Clinic, Cleveland, OH, USA |
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| Abstract: | A new class of selenonium zwitterions is prepared from the ortho- substitution of phenols with diphenylselenium bis(trifluoroacetate) 1. The zwitterions undergo a novel thermal rearrangement to produce diaryl ethers. |
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