Facile desilylative hydroxyalkylation and acylation of 1-trimethylsilylmethyl-2-pyridone期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Facile desilylative hydroxyalkylation and acylation of 1-trimethylsilylmethyl-2-pyridone

Affiliation:	1. Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal;2. CQFM-Centro de Química-Física Molecular, IN-Institute for Nanosciences and Nanotechnologies, IBB-Institute for Bioengineering and Biosciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal;3. Institut für Physik, Universität Augsburg, Universitätsstr. 1, 86159 Augsburg, Germany;4. Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10 (km 139,7), 2695-066 Bobadela LRS, Portugal

Abstract:	The title compound provides the first preparatively useful synthon for the α-carbanion of 1-methyl-2-pyridone. Desilylative hydroxyalkylation and acylation give the appropriate 1-(β-hydroxyalkyl) or 1-(β-oxoalkyl)-2-pyridones.

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