Insertion of terminal alkynes into the phosphirene ring |
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| Affiliation: | 1. Inorganic Chemistry Department, Faculty of Sciences, Autonomous University of Madrid, Madrid, Spain;2. Chemical and Environmental Engineering Department, Higher Technical School of Industrial Engineers, Polytechnic University of Madrid, Madrid, Spain |
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| Abstract: | In the presence of catalytic amounts of Pd(PPh3)4, terminal alkynes readily insert into the ring of phosphirene P-W(CO)5complexes to give the corresponding phosphole complexes. |
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