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Deoxygenation of epoxides by fluorenylidene
Affiliation:1. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK;2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;1. Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, Heilongjiang, China;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China;1. QOPN Grupo Química Orgánica de Productos Naturales, Instituto de Química, Universidad de Antioquia, Medellín, Colombia;2. PECET, Instituto de Investigaciones Médicas, Facultad de Medicina, Universidad de Antioquia, Calle 70 No. 52-21, Postal Code 0500100, Medellín, Colombia;3. Facultad de Ciencias, Universidad de Magallanes, Punta Arenas, Chile;4. Division of Medicinal and Natural Products Chemistry, The University of Iowa, Iowa City, IA 52242, USA;1. Department of Inorganic Chemistry, Faculty of Science, Charles University in Prague, Hlavova 2030, 128 40 Prague, Czech Republic;2. J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, v.v.i.; Dolejškova 3, 182 23 Prague, Czech Republic;1. State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China;2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, 163 Xianlin Road, Nanjing, Jiangsu 210023, China
Abstract:
Irradiation of 9-diazofluorene in the presence of epoxides yields fluorenone and an equimolar concentration of the alkene formed from the stereospecific deoxygenation of the epoxide.
Keywords:
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