Synthesis and reactivity of E,Z butadiene-iron tricarbonyl complexes. |
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| Institution: | 1. International Institute for Carbon-Neutral Energy Research (I2CNER),Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan;2. Department of Chemistry, Biology and Environmental Science, Faculty of Science, Nara Women’s University, Kitauoyanishi-machi, Nara 630-8506, Japan;3. Hydrogen Isotope Research Center, Organization for Promotion of Research, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan;4. Department of Applied Chemistry, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan;1. Chemistry Department, Faculty of Applied Science, Umm Al Qura University, Makkah, Saudi Arabia;2. Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt;1. Laboratory for Radiopharmacy, Department of Pharmaceutical and Pharmacological Sciences KU Leuven, Leuven, Belgium;2. Nuclear Medicine and Molecular Imaging, Department of Imaging and Pathology, KU Leuven and UZ Leuven, Leuven, Belgium;1. Cyclotron and Radioisotope Center, Tohoku University, Sendai, Japan;2. Fondazione IRCCS Istituto Nazionale dei Tumori, Milan, Italy;3. Cyclotron Research Center, Iwate Medical University, Morioka, Japan;4. Graduate School of Medicine, Tohoku University, Sendai, Japan |
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| Abstract: | The synthesis, structure and thermal stability of the E,Z butadiene-iron tricarbonyl complex 1 is reported. This complex reacts with organometallic nucleophiles in a stereoselective synthesis of functionalized E,Z dienes. |
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