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Electron-rich and electron-poor pentalene derivatives
Institution:1. Center for Strategic Utilization of Elements, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan;2. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan;3. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004, China;4. International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044, Japan;5. Global Research Center for Environment and Energy based on Nanomaterials Science (GREEN), Center for Green Research on Energy and Environmental Materials, National Institute for Materials Science (NIMS), Tsukuba 305-0044, Japan
Abstract:Bisdialkylaminoalkylidene derivatives of dihydroindeno2,1-a]indene as electron-donors, and dihydroindeno-2,1-a]indene-5,10-dione-biscyanoimines and bisdicyanomethylene-dihydroindeno1,2-b]fluorenes as acceptors have been prepared and found to form charge transfer complexes with interesting electrical conductivities.
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