A facile and highly stereoselective synthesis of (2E)-, (2E,4E)-unsaturated amides and related natural products |
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| Affiliation: | 1. Center for Environment, Health and Welfare Research, Korea Institute of Science and Technology, Hwarangno 14 gil 5, Seoul, Seongbuk-gu 136-791, Republic of Korea;2. Graduate School of Energy Environment Policy and Technology, Korea University, Anam-ro 145, Seoul, Seongbuk-gu 136-701, Republic of Korea |
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| Abstract: | A facile synthesis of (2E)-, (2E, 4E)-unsaturated amides was achieved via arsonium bromides with high stereoselectivity. Its application to the synthesis of related natural products 4 and 5 is also reported. |
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