Asymmetric oxidation of prochiral selenides to optically active selenoxides |
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| Institution: | 1. Guizhou Engineering Center for Innovative Traditional Chinese Medicine and Ethnic Medicine, Guizhou University, Guiyang, 550025, China;2. State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming, 650201, Yunnan, China;1. Ronzoni Institute for Chemical and Biochem. Research, via G.Colombo 81, 20133 Milano, Italy;2. Fondazione Istituto Nazionale dei Tumori di Milano, via Venezian 1, 20133 Milano, Italy;1. Department of Pharmacology, School of Basic Medical Sciences, Cheeloo College of Medicine, Shandong University, Jinan, Shandong 250012, China;2. Shandong Key Laboratory of Water Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Shandong University, Qingdao, Shandong 266237, China;3. School of Medicine, Cheeloo College of Medicine, Shandong University, Jinan, Shandong 250012, China;4. Department of Urology, Qilu Hospital, Cheeloo College of Medicine, Shandong University, Jinan, Shandong 250012, China;5. College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;6. School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China |
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| Abstract: | Oxidation of 1,1-diphenyl-1-methoxy-2-phenylselenylethane and of 1,1-diphenyl-1-methoxy-2-(o-methoxy)phenylselenylethane with the Sharpless reagent afforded the corresponding selenoxides with moderate optical yields. |
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