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Dehydration of alcohols catalyzed by copper(II) sulfate adsorbed on silica gel
Affiliation:1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing, China;2. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China;3. University of Chinese Academy of Sciences, Beijing, China
Abstract:Copper(II) sulfate adsorbed on silica gel efficiently dehydrated secondary and tertiary alcohols under mild conditions to give olefins. The rate of dehydration of tertiary alcohols is much faster than that of secondary alcohols.
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