Pd(II)-catalyzed para-selective C-H arylation of monosubstituted arenes |
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| Authors: | Wang Xisheng Leow Dasheng Yu Jin-Quan |
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| Institution: | Department of Chemistry, The Scripps Research Institute, La Jolla, California 92037, United States. |
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| Abstract: | Pd-catalyzed highly para-selective C-H arylation of monosubstituted arenes (including toluene) is developed for the first time using an F(+) reagent as a bystanding oxidant. This finding provides a new retrosynthetic disconnection for para-substituted biaryl synthesis via C-H/C-H cross-coupling. |
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