Palladium-catalyzed conjugate addition of terminal alkynes to enones |
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| Authors: | Villarino Lara García-Fandiño Rebeca López Fernando Mascareñas José L |
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| Institution: | Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Unidad Asociada al CSIC, Universidad de Santiago de Compostela, 15782, Santiago de Compostela, Spain. |
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| Abstract: | A practical protocol for the hydroalkynylation of enones using Pd catalysis is reported. The reaction proceeds efficiently with a variety of alkynes as well as with several cyclic and acyclic enones, providing synthetically relevant β-alkynyl ketones in good to excellent yields. |
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