A polarographic cell system with a novel temperature-controlled reference electrode for the determination of kinetic parameters of electrode reactions |
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| Authors: | Crow D R Sharp J G |
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| Affiliation: | Department of Physical Sciences, The Polytechnic, Wolverhampton, England. |
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| Abstract: | An improved experimental arrangement for the determination of kinetic data relating to polarographic reductions is described. The significant feature is the constant-temperature reference electrode; its construction and use in this context are described. A comparison is made of the more realistic results obtained by these means, with those obtained with a more conventional cell where the temperature of the reference electrode is varied with that of the working solution. |
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