Chelatometric determination of calcium and magnesium in iron ores, slags, anorthosite, limestone, copper-nickel-lead-zinc ores and divers materials |
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Authors: | Hitchen A Zechanowitsch G |
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Institution: | Mineral Sciences Laboratories, Canada Centre for Mineral and Energy Technology, Department of Energy, Mines and Resources, Ottawa, Canada. |
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Abstract: | Chelatometric methods for the determination of calcium and magnesium in iron ores, slags, anorthosite, copper-nickel-lead-zinc ores and various other materials are described. Potential interfering elements are masked with triethanolamine and potassium cyanide. In one aliquot calcium is titrated at pH > 12, with calcein and thymolphthalein mixed indicator and in another aliquot calcium and magnesium are titrated in ammonia buffer, with o-cresolphthalein complexone screened with Naphthol Green B as indicator. The results compare favourably with certified values for reference materials of diverse nature. |
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