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Interconnection between chain growth in the Herington scheme and secondary reactions involving ethylene in the Fischer-Tropsch synthesis
Authors:M. N. Yakubovich
Affiliation:(1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine
Abstract:It is shown that C4+ hydrocarbons are predominantly formed from intermediates containing three carbon atoms at high values of chain growth probability, but result from interactions of two carbon fragments at low values of chain growth probability. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 3, pp. 178–183, May–June, 2006.
Keywords:Fischer–  Tropsch synthesis  mechanism  secondary reactions  catalysts
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