Structure and location of proton hydrates in Triton N-42 reverse micelles during injection solubilization of HCl solutions |
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Authors: | T Yu Podlipskaya A I Bulavchenko |
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Institution: | 1.Nikolaev Institute of Inorganic Chemistry, Siberian Branch,Russian Academy of Sciences,Novosibirsk,Russia |
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Abstract: | A Fourier IR spectroscopic study has shown that during injection solubilization* of HCl solutions (V s/V o = 1.0-3.5 vol.%) at a concentration of 1-4 M by Triton N-42 reverse micelles in n-decane, the number of water molecules bound to protons is equal to 2.7±0.1. Protons form H7O3 + (70%) and H5O2 + (30%) cations in equilibrium, which are localized in the aqueous cores of the micelles. |
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