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A new synthesis of dienone lactones using a combination of hypervalent iodine(III) reagent and heteropoly acid
Authors:Hata Kayoko  Hamamoto Hiromi  Shiozaki Yukiko  Kita Yasuyuki
Institution:Graduate School of Pharmaceutical Sciences, Osaka University, 1-6, Yamada-oka, Suita, Osaka 565-0871, Japan.
Abstract:The oxidation of non-phenolic alkanoic acid derivatives to oxygen heterocycles was investigated; a new oxidative route to dienone lactones has been developed using a combination of hypervalent iodine(III) reagent, phenyliodine(III) bis(trifluoroacetate)(PIFA), and heteropoly acid (HPA).
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