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| 西红花有效成分合成研究进展 | |
| 引用本文： | 张宏,张俊国,张伶,颜钫,陈放.西红花有效成分合成研究进展[J].化学研究与应用,2009,21(6). |
| 作者姓名： | 张宏 张俊国 张伶 颜钫 陈放 |
| 作者单位： | 1. 四川师范大学生命科学院,四川,成都,610068;四川大学生命科学学院,四川,成都,610064 2. 四川师范大学化学与材料学学院,四川,成都,610068 3. 四川大学肿瘤生物治疗中心,四川,成都,610041 4. 四川大学生命科学学院,四川,成都,610064 |
| 摘 要： | 西红花主要有效成分为西红花酸和西红花糖苷,论文综述西红花酸和西红花糖苷生物合成和化学合成方法.在生物合成中最关键的是用葡萄糖糖基转移酶作催化剂将西红花酸转化为西红花糖苷;共轭多烯链化合物是合成西红花有效成分的起始物,在论文中概述了几种通过Wittig和Wittig-Horner 反应合成共轭多烯链化合物的路线. |
| 关 键 词： | 西红花 西红花酸 西红花糖苷 生物合成 化学合成 |
Study on synthesis of active compounds from saffron |
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| ZHANG Hong,ZHANG Jun-guo,ZHANG Ling,YAN Fang,CHEN Fang.Study on synthesis of active compounds from saffron[J].Chemical Research and Application,2009,21(6). | |
| Authors: | ZHANG Hong ZHANG Jun-guo ZHANG Ling YAN Fang CHEN Fang |
| Institution: | 1.College of Life Science Sichuan Normal University;Chengdu 610068;China;2.College of Life Science Sichuan University;Chengdu 610064;3.College of Chemistry and Materials Sichuan Normal University;4.Center of Tumour Living Therapeutic Sichuan University;Chengdu 610041;China |
| Abstract: | The biological and chemical synthesis methods of crocetin and crocins,which are major biological active compounds in saffron are summarized in this article.The final step in the biosynthesis is transformation from crocetin into crocins by glucosylation reactions,which are catalysed by glucosyltransferases(GTases).We described some short and efficient synthetic routes to obtain polyene chains by Wittig and Wittig-Horner reactions,which are the starting materials for the syntheses of the active compounds of s... |
| Keywords: | saffron crocetin crocins biological synthesis chemical synthesis |
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