| 掺Tb3+聚醋酸乙烯乳液的制备及性质研究 |
| |
| 引用本文： | 林美娟,王文,章文贡. 掺Tb3+聚醋酸乙烯乳液的制备及性质研究[J]. 广州化学, 2004, 29(1): 20-23 |
| |
| 作者姓名： | 林美娟 王文 章文贡 |
| |
| 作者单位： | 福建师范大学,化学与材料学院,福建,福州,350007;福建师范大学,化学与材料学院,福建,福州,350007;福建师范大学,化学与材料学院,福建,福州,350007 |
| |
| 摘 要： | 在PVAc乳液聚合过程,将一定比例的三氯化铽(TbCl3)溶液与醋酸乙烯(VAc)单体同步滴入聚合体系,获得掺Tb3+ 离子的PVAc乳液, 研究Tb3+离子对PVAc乳液性能的影响。研究表明,Tb3+ 离子对PVAc的颗粒形貌、大小及其质量指标影响不大,但对发光性能有一定的影响,即掺Tb3+ 离子的PVAc会产生很强的Tb3+ 离子特征荧光,且随Tb含量的提高,其荧光强度随之增强,无荧光浓度猝灭现象。
|
| 关 键 词： | 聚醋酸乙烯乳液 Tb3+离子 荧光 |
| 文章编号： | 1009-220X(2004)01-0020-05 |
| 修稿时间： | 2003-09-17 |
Preparation and Properties of Polyvinyl Acetate Emulsion Doped with Tb3+ Ion |
| |
| LIN Mei-juan,WANG Wen,ZHANG Wen-gong. Preparation and Properties of Polyvinyl Acetate Emulsion Doped with Tb3+ Ion[J]. Guangzhou Chemistry, 2004, 29(1): 20-23 |
| |
| Authors: | LIN Mei-juan WANG Wen ZHANG Wen-gong |
| |
| Abstract: | In the polymerization process, trichloride terbium (TbCl3) and vinyl acetate monomer were added into polymerization system in step. Polyvinyl acetate emulsion (PVAc) doped with Tb3+ ion was prepared, and the effect of Tb3+ ion on the properties of PVAc was studied. The results show that Tb3+ ion has little influence on the grain morphology, size and quality of PVAc, but PVAc doped with Tb3+ ion has fluorescence property. It can emit strong Tb3+ ion characteristic fluorescence, and the fluorescent strength is increased with increasing Tb3+ content. |
| |
| Keywords: | polyvinyl acetate emulsion Tb3+ ion fluorescence |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
