Reaction gas chromatography-mass spectrometry. Communication 5. Determination of the position of the double bond in alkenes using selective deuteration in the column of a gas chromatograph-mass seectrometer

Conclusions A method was proposed for determining the position of the double bond in alkenes based on the comparative analysis of the mass spectra of the corresponding alkanes and vicinal dideuteroalkanes, obtained directly during the hydrogenation and selective deuteration of the alkenes in a specially developed reaction column.Cf. [1] for Communication 4.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya., No. 3, pp. 581–584, March, 1985.