Nuclear magnetic resonance of oriented54Mn nuclei in antiferromagnetic MnCl2 · 4H2O |
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Authors: | A Kotlicki B G Turrell |
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Institution: | (1) Department of Physics, University of British Columbia, V6T 2A6 Vancouver, BC, Canada;(2) Present address: Institute of Experimental Physics, Warsaw University, Hoza 69, 00-681 Warsaw, Poland |
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Abstract: | Nuclear magnetic resonance of oriented54Mn nuclei in antiferromagnetic MnCl2 · 4H2O has been observed. The first two lines of the sextuplet split by quadrupole interaction are at frequencies 500.4 and 514.7 MHz, implying a hyperfine field of 643(5) kG. The stronger line at 500.4 MHz has a half-width at half maximum of 60 kHz and is shifted downward and split in frequency on application of a magnetic field. The nuclear spin-lattice relaxation time is dependent both on the applied field and the size and/or quality of the crystal. |
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