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An efficient method for the preparation of glycosides with a free C-2 hydroxyl group from thioglycosides |
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| Authors: | Hai Yu Harry E Ensley |
| Institution: | aDepartment of Chemistry, Tulane University, New Orleans, LA 70118, USA |
| Abstract: | A new and efficient method to produce glycosides with a free C-2 hydroxyl group through 1,2-acyl group migration which occurs during the hydrolysis of 4,6-benzylidene protected thioglycosides has been developed. The acyl transfer products allow for further elaboration. |
| Keywords: | thioglycoside hydrolysis 1 2-acyl migration |
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