Catalytic Properties of (Fe,Al)-MCM-41 in Conversion of CO and Light Alkanes with Participation of Nitrogen Oxides |
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| Authors: | Orlik S. N. Pop G. Ganea R. Ostapyuk V. A. Alekseenko L. M. |
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| Affiliation: | (1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 Nauky Prospekt, 03028 Kyiv, Ukraine;(2) S.C. ZECASIN S.A., 202 Spl. Independentei, Sector 6, 77208 Bucharest, Romania |
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| Abstract: | We used X-ray phase analysis, IR, X-ray photoelectron, and NMR spectroscopy to characterize a synthesized mesoporous material (Fe,Al)-MCM-41. As a result of a certain combination of structural, acidic, and oxidation–reduction properties of the surface, (Fe,Al)-MCM-41 exhibits catalytic activity in reactions with participation of nitrogen oxides, in particular partial oxidation of propane by nitrogen(I) oxide to isopropanol. |
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| Keywords: | mesoporous iron-containing material structural acidic redox properties of a surface reactions with participation of nitrogen oxides |
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