Exploitation of gradient techniques in flow injection analysis

Summary Founded on the key role of dispersion, controlled in space and time, the FIA gradient techniques are based on the feasibility of identifying and selecting reproducibly suitable sections of the time/concentration matrix represented by the dispersed sample zone and exploiting the specific concentrations at these points for analytical purposes. The characteristics and common theme of these gradient procedures — comprising gradient dilution and calibration, stopped flow reaction rate measurement, titrations, gradient scanning, and systems associated with simultaneous injection of two zones which completely or partially overlap thereby permitting the execution of selectivity studies and standard addition procedures — are briefly reviewed.

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Ausnutzung von Gradientenverfahren bei der Fließinjektionsanalyse