Retention vs van der walls volume,pi-energy and hydrogen-bonding energy effects and enthalpy in liquid chromatography |
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Authors: | T Hanai A Jukurogi J Hubert |
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Institution: | (1) Gasukuro Kogyo Inc., 237-2 Sayamagahara, 358 Iruma, Japan;(2) Department de Chimie, Université de Montréal, PC6210, Succ. A, H3C 3V1 Montréal, Québec, Canada |
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Abstract: | Summary The logarithm of capacity ratios (logk’) of alkanes, alkyl alcohols, alkylbenzenes, halogenated benzenes and polyaromatic
hydrocarbons are measured in reversedphase liquid chromatography at several temperatures using an octadecyl-bonded silica
gel as the packing and acetonitrile/water mixtures as the eluent.
The Δ (logk’) values are related to their van der Waals volumes, pi-energy and hydrogen-bonding energy effects and their enthalpies.
The difference between the observed capacity ratios and the capacity ratios predicted from van der Waals volumes, pi-energy
and hydrogen-bonding energy effects can be explained due to enthalpy effect of larger molecular size compounds.
Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984 |
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Keywords: | Reversed-phase liquid chromatography Van der Waals volume Pi-energy Hydrogen bonding energy Enthalpy |
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