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In vivo participation of artificial porphyrins in electron-transport chains: electrochemical and spectroscopic analyses of microbial metabolism
Authors:Mori Shigeki  Ishii Kazuyuki  Hirakawa Yuichiro  Nakamura Ryuhei  Hashimoto Kazuhito
Institution:HASHIMOTO Light Energy Conversion Project, ERATO/JST, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan.
Abstract:The effects of artificial porphyrins on the electron-transport chains of living microbes were investigated. The participation of porphyrins in the microbial electron-transport chains was demonstrated by spectroscopic and current-generation measurements. Large enhancement of the microbial current generation was accomplished by adding a cationic water-soluble manganese porphyrin as an electron mediator.
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