In vivo participation of artificial porphyrins in electron-transport chains: electrochemical and spectroscopic analyses of microbial metabolism |
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Authors: | Mori Shigeki Ishii Kazuyuki Hirakawa Yuichiro Nakamura Ryuhei Hashimoto Kazuhito |
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Institution: | HASHIMOTO Light Energy Conversion Project, ERATO/JST, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan. |
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Abstract: | The effects of artificial porphyrins on the electron-transport chains of living microbes were investigated. The participation of porphyrins in the microbial electron-transport chains was demonstrated by spectroscopic and current-generation measurements. Large enhancement of the microbial current generation was accomplished by adding a cationic water-soluble manganese porphyrin as an electron mediator. |
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