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CuZnMgAl水滑石衍生金属氧化物对废水中Pb(Ⅱ)的吸附
引用本文:王军涛,陈兰萍,詹正坤.CuZnMgAl水滑石衍生金属氧化物对废水中Pb(Ⅱ)的吸附[J].化学研究,2012(1):39-42.
作者姓名:王军涛  陈兰萍  詹正坤
作者单位:[1]咸宁学院化学与生命科学学院,湖北咸宁437100 [2]华中师范大学化学学院,湖北武汉430079
基金项目:基金项目:咸宁学院第四期大学生课外科技项目,咸宁学院校级青年科研项目(KY10051).
摘    要:采用共沉淀法合成了不同物质的量之比的CuZnMgAl水滑石(CuZnMgAl-HT),采用X射线衍射仪和热分析仪分析了其晶体结构和热稳定性;将CuZnMgAl-HT的焙烧产物作为吸附剂,测定了其对废水中Pb(Ⅱ)的吸附性能.结果表明,最佳吸附条件为温度30℃,pH 6.0,初始浓度80mg/L,水滑石前体Cu、Zn、Mg、Al的金属物质的量之比为1∶1∶4∶2,吸附时间40min时,相应的吸附率可达95.23%.

关 键 词:水滑石  金属氧化物  二价铅  吸附

Adsorption lead ion in waste water by metallic oxides derived from CuZnMgAl-hydrotalcites
WANG Jun-tao,CHEN Lan-ping,ZHAN Zheng-kun.Adsorption lead ion in waste water by metallic oxides derived from CuZnMgAl-hydrotalcites[J].Chemical Research,2012(1):39-42.
Authors:WANG Jun-tao  CHEN Lan-ping  ZHAN Zheng-kun
Institution:1 .School of Chemistry and Life Science, Xianning College, Xianning 437100, Hubei, China; 2. School of Chemistry, Central China Normal University, Wuhan 430079, Hubei, China)
Abstract:CuZnMgAl-hydrotalcites (CuZnMgAl-HT) with different metal molar ratios were synthesized by copreeipitation method. The crystal structure and thermal stability of as-synthesized CuZnMgAl-HT were analyzed by means of X-ray diffraction and thermal analysis. More- over, as-synthesized CuZnMgAl-HT was calcinated, and the adsorption performance of the calcinated product, compound metal oxides, for Pb( II ) in waste water was examined. The optimum condition for adsorption is suggested as temperature 30 ℃, pH value 6.0, initial lead ion concentration 80 mg/L, CuZnMgAl-HT precursor metal molar ratio of Cu,Zn,Mg,Al was 1 : 1 : 4 : 2, and adsorption time 40 min. Corresponding adsorption rate reaches as much as 95.23%
Keywords:hydrotalcite  metallic oxides  lead( II )  adsorption
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