| Synthesis, Crystal Structure and Magnetic Properties of a 1-D Polymer, [Cu(NITpPy)_2(H_2TCB)(H_2O)]·2H_2O |
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| 作者姓名： | 王利亚 李立存 廖代正 姜宗慧 阎世平 |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China，Department of Chemistry，Nankai University，Tianjin 300071，China State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China，Department of Chemistry，Nankai University，Tianjin 300071，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (Nos .2 0 1710 2 5and 90 10 10 2 8) |
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| 摘 要： | IntroductionNitronylnitroxidesactingasusefulparamagneticbuild ingblockshavebeenextensivelyusedtoassemblemolecularmagneticmaterialsinthepastfewyears .1 4 However,theirweaklybasiccharacterstronglylimitstheircoordinationabili ty .Thishasledtothedevelopmentoffunctionalizednitronylnitroxideradicalsinwhichastrongcoligandisincorporated .Amongfunctionalizednitronylnitroxideradicalligands ,thepyridyl substitutednitroxideradicalsareextensivelyusedtoassembleextendedcoordinationgeometrieswithchangingmagne…
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