Abstract: | The synthesized aromatic polyurethane (APU)-based all-solid-state (ASS) pH sensor was developed with the same APU-based reference site in an ASS multi sensing electrode. The best analytical performance (the linear range of pH 3.0–11.5, slopes of 57 mV pH−1) was obtained with the membrane composition of 33:66:1 (wt.%) of APU/plasticizer (NPOE)/ionophore (N,N-dioctadecylmethylamine) with the addition of lipophilic additive (KTpClPB, 5 mol.%). This ASSE exhibits more advantages of increasing stability, reducing membrane resistance and reducing anion interference. |