Synthesis of monoglycosyl diglycerides and their derivatives |
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Authors: | S. G. Batrakov E. F. Il'ina A. G. Panosyan |
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Affiliation: | (1) M. M. Shemyakin Institute of Bioorganic Chemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The Koenigs-Knorr condensation of 1,2- and 2,3-di-O-benzyl-sn-glycerols with acetobromohexapyranoses results in the formation of practically only 1,2-trans-glycosides. The latter have been used for the synthesis of a number of monoglycosyl diglycerides with diglyeride moieties with L and D configurations.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 643–649, March, 1976. |
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