Quantitative Generalization of Solvent Effect on Radical Halogenation of Hydrocarbons |
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| Authors: | R. G. Makitra G. G. Midyana E. Ya. Pal’chikova |
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| Affiliation: | (1) Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, Lviv, Ukraine;(2) Department of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79053, Ukraine |
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| Abstract: | The dependences of the isomer ratio in photochemical chlorination of 2,3-dimethylbutane and of the selectivity in photochemical bromination of a mixture of cyclopropylbenzene and toluene may be described by linear multiparameter equations. In the first case, the determining factors are the nonspecific solvation power and molar volume of the solvent, and in the second, the molar volume and cohesion energy density.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 7, 2005, pp. 967–972.Original Russian Text Copyright © 2005 by Makitra, Midyana, Pal’chikova. |
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