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Palladium on activated carbon catalyzed reductive amination of aldehydes and ketones by triethylsilane
Authors:Maryam Mirza‐Aghayan  Mahdieh Molaee Tavana  Mahshid Rahimifard  Rabah Boukherroub
Institution:1. Chemistry and Chemical Engineering Research Center of Iran (CCERCI), Tehran, Iran;2. Institut de Recherche Interdisciplinaire (IRI, USR 3078), Villeneuve d'Ascq, France
Abstract:Various aldehydes and ketones were efficiently transformed into the corresponding amines using amine derivatives in the presence of triethylsilane and a catalytic amount of palladium on activated carbon in ethanol. The proposed method provides a one‐pot synthesis of various amines in excellent yields after short reaction times. Copyright © 2013 John Wiley & Sons, Ltd.
Keywords:Pd/C  triethylsilane  aldehyde  ketone  reductive amination
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